Hi,
I am using LMV751 as an input buffer. Pin5 3.3V, pin 4 connected to pin1 output to an ADC, pin3 input from 0 to 3.0V, pin2 GND. When input voltage (pin3) is higher than 2.83V, the output is 3.3V suddenly. If the input voltage is 2.82V, the output is 2.823V, which is OK. From the datasheet "SNOS468E –AUGUST 1999–REVISED MARCH 2013" it seems, that the maximum input voltage is supply voltage, which in my case would be 3.3V.