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Hi Jimmy,
Your calculation method for the graph is correct but we don't recommend to use the device outside its data sheet max limits as TI can't guarantee the device performance in such cases. The working voltage is typically limited to a lower value due to smaller package size and many applications have other limitations such as Creepage distance, reinforced vs basic insulation, etc.
That said, since your required voltage is 450 Vrms, which is only marginally above 400 Vrms, I don't foresee any issues and the device should be able to sustain this stress.
Thanks,
Saleem Marwat