I would like to know if I can simply replace MSP430F5229 by MSP430F5252? I will need to have more RAM for my project.
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It is not a simple answer for just anybody to be able to answer for you, for we do not know anything about your system application.
For starters, the two parts differ in the number of USCI modules and the ADC module is different. You will need to analyze the differences in the parts with respect to the needs of your application.
I'm sure that you can refer to pinout diagrams of the two devices and compare those to know if they are otherwise pin compatible. It is a simple exercise and I'm not inclined to do that for you.