Do you have value for the time between EN pin becoming active until Vout becoming active?
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Thank you for sharing your schematic with us. I will go ahead into the lab to show you real data. Please give me a day so I can collect the data.
On the meanwhile, from simulations I obtained the following:
The red is Ven and blue is Vout. From the point where EN is completely high to Vout completely high ~146us
From EN high to 90% of VOUT the time shows 131us.