I found Vout of TPS3619-33DGKR was not switched to the VBAT(backup battery) when VDD experienced a power drop. Check the attached picture.
When VDD(Ch#1) goes down from 3.3V to 0.8V, the VOUT(Ch#3) seems to follow and track the VDD, Why the VOUT is not switched to the VBAT?