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TPS2640: Protection diodes

Part Number: TPS2640
Other Parts Discussed in Thread: TVS2701

Hi team,

1)

can you tell what is the purpose and how to select schottky diode on output, page 38 figure 11-1 in Datasheet? 

2) In what scenario can we use bidirectional TVS2701 instead of SMC diodes for selected diodes below? (Vin_max working voltage is 25V)

is it ok to use TVS2701 if surge level is class2 1kV 42Ohm?

Best Regards,

d.