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Cannot get access for sample with company email address

I keep trying to get access for samples and it is denied. I dont understand why. We are a real company that purchase $500K of ics and fets from TI a year. I have requested with the company email address and it keeps getting denied. We are not a University or personal account. They give zero response as to what is going on. This is very frustrating. Its not a matter of cost for the samples, its all the additional work I have to go through with purchasing on our side just to prototype circuits that I am trying to avoid.