Other Parts Discussed in Thread: CC3235S, TMDSEMU110-U
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For programming of CC3235MOD you need to connect UART pins a module pins 46, 47 (pins 55, 57 of internal QFN). There is no option for usage of another pin, because pinnumbers are hardcoded inside ROM bootlaoder.
Yes, you can use TMDSEMU110-U debug probe for debugging of you hardware as well. But it costs more than LaunchPad. There is no reason to use TMDSEMU110-U is you have CC3235S LaunchPad unless you want to have troubles with connection and spend more money.
But if you still want to use TMDSEMU110-U, here are resources: