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TPS259472ARPWR: Questions about temperature range of device relative to the UL and CB certificates

Part Number: TPS2549

It appears from the relevant standards in the certificates, that this component has an upper temperature range limit of 70 °C per the UL component certification (assuming that this means an ambient temperature), but the datasheets seem to imply that it can have a much higher Junction temperature. Our intended use for this product will have it in an environment that may occasionally reach (and possibly exceed briefly) 70°C. Do you have any data relating Ambient temperature to Case temperature (which we can measure) to Junction temperature (which we cannot measure) under different conditions? This way we could do some testing on our own and make sure that our case temperature does not exceed the rating. Do you have any test data showing the reliability of these parts (TPS259472ARPWR) at ambient temperatures over 70C and maybe a de-rating curve? 

Thanks!