Hi there.
Looking at the block diagram in the datasheet, it is evident that the buck converter works only when the system is being powered by an external source (VBus) and not when it is being powered from the battery. Can you please confirm this? Would this require an additional buck converter to be added to the system output of this charging IC to ensure that the end system always receives a regulated supply? If so, then this makes this charging IC unfit for the applications mentioned on the first page of the datasheet.