I've assembled a basic design, based on figure 10-3 of the datasheet. The only significant difference is I don't have anything connected to the NTC pin, but I have disabled thermal foldback in the GUI.
Firmware was loaded into the device with an EEPROM programmer and I can successfully update it via the USB endpoint when I power it up in update mode.
From a cold start, the device appears to power up and draws around 7mA. I can see a 400kHz signal on the SYNC pin, the LDO's all seem to output the right voltage.
However, there is no sign of any activity output on the USB port.
Are there some recommended troubleshooting steps?