I'm got 2 almost identical circuits based on the TPS54325. One is generating 3.3V and the other is genrating 5.0. The capacitor between Vfb and the inductor is 22pF for the 5.0V and 100pF for the 3.3V circuit. The only other difference is the upper feedback resistor.
Both circuits are fed from the same 12V source and right now I do not have any load connected. The 3.3V circuit fires right up but the 5.0V circuit very briefly come on (no scope on the production floor here but I have a LED on the output). PG is 0V and the high side of the enable pull up is 12V. As soon as I probe pin 7 or the side of the pull-up resistor connected to pin 7, with my volt meter the circuit starts working and stays working until I remove power and try again.
Maybe because it's Friday afternoon but what's up?