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How to Understand the Maximum Duty Cycle TPS54335 ?

I found on the table TPS54335/6 was defined as 90% as the maximum duty cycle.

How to understand it?  Does it support all corner condition for 3A operating? 

Can I caculate the Vout/VIN less than 90%?

Or this 90% is only ensured on EVM about the SW waveform, and for minimum VIN for given Vout should be higher than 1.1 times that of Vout?