It isn't clear from the documentation how much higher VIN needs to be over VOUT. I can only make inference from the duty-cycle calculation.
My application is VIN = 2x LION batteries in series, sum voltage of 8.4V Max down to 6.0V, VOUT = 5.0V with load of 200mA.
Ran a battery life test with static resistive load on +5V output at 100mA. Over 24 hour period, the pair of batteries discharged from 8.29V to 7.0V at which time one of the batteries failed due to overcurrent. The surviving battery was still good at 3.5V. This has happened twice.
How can I determine at what point the LM22672 will enter what the datasheet under "Precision Enable and UVLO" calls "excessive battery discharge...or abnormal device operation in applications where the input voltage falls to low"?