For the TPS61235RWLR, we had concerns similar to those of the TPS63031DSKT. Our first concern was over having two grounds. The datasheet recommends having two grounds for AGND and PGND. However, the typical application schematic shows both grounds being connected to one another. For the EN, we are unsure if using the Li-ion battery’s voltage is sufficient or a 3.3 V bus voltage is necessary.