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LMR14020: Sub-harmonic instability.

Part Number: LMR14020

I put together a design using the LMR14020 which I believe to be unstable. I simulated the design with the PSpice AC and transient models provided on TI's website. According to the averaged model the phase margin is 59d and the gain margin is 45dB. The design worked beautifully in the transient simulation as well for line and load steps. Upon building a prototype and testing it, I found the converter will not regulate at a duty cycle above 50%. Any suggestions? At present I am looking for a different chip with which I can implement my own compensation.