I look for TPS543B20 max duty cycle vs frequency chart/calculation
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Igor,
TPS543B20 has a relatively long minimum off time. For typical value, max duty cycle is given by:
Dmax = 1 - (Toffmin * Fsw) where Toffmin = 250 nsec typical
So for Fsw = 300 kHz, Dmax = 92.5%, for Fsw = 2 MHz, Dmax = 50%