Hi,
Based on the datasheet, the complete shutdown occurs only if the over current condition last for long time enough to trigger thermal limiting. So, we should not expect Vout become 0V immediately when a overcurrent load is applied.
Meanwhile, can you check if the behavior as below when the overcurrent load is added to the output of TPS2546?
CH1: TPS2546 OUT voltage
CH2: TPS2546 OUT current
THanks!
Antony