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TPS54531: Vstart and Vstop calculation review

Part Number: TPS54531

Hi 

We would like to design VSTART=5.5V and  VSTOP=5.0V

after calculation we get  R10 =167K, R11=47.2K and our schematics as below.

However, using the above R10 and R11 value to do real test we see VSTART=6.33V and VSTOP=5.2V. this is different from our calculation result. 

Would you help review anything wrong with our schematics below ? 

Also is it required that Vin need to be > Vout + 2V ?