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TPS61170: quadruple circuit

Part Number: TPS61170

Hi Team,

Here is a question from customer. 

Customer use TPS61170 to do a boost+ quadruple circuit  ( using diode and cap, similar with the double circuit shown in fig 20 in datasheet)  to achieve 90Vout. But they find issue that Vout cannot be above 77V  and SW is changing between Dmax to small duty cycle regularly. Then they change the quadruple circuit to triple circuit and it can works but since Vout is high, SW spike is beyond spec. 

So just want to get some suggestions on why the quadruple circuit cannot work. Thanks. 

BRs

Given