We used webench to create a design to take 10V to 36V in and output a steady 28V at up to 6.5A.
We made a board to this exact design (I think). During testing we found that for input voltages from 10 to 28V this board works well, however above 28V the Vout pretty much follows Vin, for example Vin at 32V gives a Vout of 30.6V.
Any ideas?