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TPS630250: Backup Power System

Part Number: TPS630250
Other Parts Discussed in Thread: TPS63020, , TPS63802

Can I use the TPS630250, instead of TPS63020, for a backup power system? The system examples for TPS63020 include a Supercapacitor Backup Power Supply. I would like to utilize this design with the smaller TPS630250. Is there any reason this will not work?