I met the same problems. I am using same oring mode with above schematic.
the different is, I found, when the Vout is higher than Vin 0.6V, LM66100 could turn of instead of 80mV.
Another one interesting is, if power on Vout first, then power on Vin, this chip is off. it could be understood, CE is pull high if power on Vout first.
if power on Vin first, then power on Vout, it can not turn off until Vout-Vin higher than 0.6V.
last point, I cannot understand of the spec, what does Vfwd means, does this mean Vce> 0.1V to 1.1V? what's the relationship with Vfwd?
can you help please?