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TI does not provide custom programming services with different default output voltages for the TPSM846C23.
For applications that will not use standard ULINEAR16 formatting of VOUT_COMMAND, the initial output voltage and be set by placing a resistor from FB to GND using the default 0.5V reference voltage to set the initial output voltage using the equation:
Rbias = 10k ( Vout / 0.5V - 1)
This will change the scaling of VOUT_COMMAND from 2^-9V (1.953mV/LSB) to (1+10k/Rbias) * 2^-9V/LSB
Alternately, VOUT_COMMAND can be reprogrammed, either as a discrete module, or after assembly, and the updated VOUT_COMMAND value can be stored to NVM using the STORE_DEFAULT_ALL PMBus command.