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Hi Diego,
Thanks for your question.
The main difference between the two devices are in terms of performance. TLV62085 is a cost optimized device, whereas TPS62085 is an high performance device.
This difference can be seen for example from the output voltage accuracy (TPS62085 guarantees a VOUT accuracy of 1% in PWM mode) and power good threshold.
Please ask again if you need further support.
Thanks,
Stefano
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