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TMP451-Q1: Question about PNP transistor connenction

Part Number: TMP451-Q1

Hi team,

We have two questions about TMP451-Q1.

1. For below connection, it says this has better settling time, what does settling time mean here? Why PNP transistor will have better series resistance cancellation in this connection? 

2. If the sensing is mainly by PN junction, can we use diode PN for replacement? 

Thanks.

Johnny