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Hi Madhu,
CC2530 provides two IEEE Address spaces, Primary and Secondary. Primary IEEE Address is created uniquely for each device within the range secured by TI and assigned to the device at production. Primary IEEE cannot be changed. However if Secondary IEEE Address is set to non-0xFFFFFFFFFFFFFFFF value, Z-Stack will use the Secondary IEEE Address instead of Primary IEEE Address. Secondary IEEE Address is 0xFFFFFFFFFFFFFFFF out of the box, but can be programmed by using either SmartRF Flash Programmer or function call osal_nv_write() with the item index ZCD_NV_EXTADDR as one of the parameters.
For more information, please see Chapter 7.2 of "Z-Stack User's Guide - CC2530DB.pdf" distributed with Z-Stack.
- Cetri