As I understand, there is a possibility that the PCA9546A part becomes unresponsive if POR fails due to slow Vcc ramp.
My questions are:
1. Will the external hardware reset unlock the communication (it looks like yes);
2. More importantly, will the "I2C software reset" flush the locked state machines, and unlock the part for further I2C communication?
I understand the "I2C sofware reset" as follows (per ADA AN-686 appnote):