Hello,
According to datasheet of TPS25750, TI define ambient temperature of TPS25750D according to usecase.
I would like you to confirm about available ambient temperature for following case.
* Ipp_5v ≦ 3A, Ipp_hv ≦ 5A and Ipp_cable ≦ 315mA
I think that this is most likely usecase (Sink 100W, Source 15W)
Best Regards,