I found a solution and want to share it. I am using a MSP4305419A USI in the UART mode with 'desired' baud rate of 460,800 bps (7-data, 1-stop, no parity)
Sending packets of 32 bytes I was experiencing errors once every few thousand packets. Multiple receiver devices all pointed to the MSP transmit as the BAD guy.
At ~25Mhz MCLK (DCO @ 762 multiplier off low freq 32,768Hz crysta)l and SMCK at divide by 1 the baud rate generator required MODULATION. The modulation and bit error is the apparent problem.
The solution was to pick a DCO multiplier that set the MCLK to a frequency that is VERY close to integer multiple of 460,800Hz.
Crystal freq of 32,768 Hz * 731 = 23,953,408 Hz (MCLK)
23,953,408 Hz / 52 = 460,642 Baud Rate Error of 0.034%
The MCLK and CPU run at 23.9 Mhz (below the faster 25Mhz possible) but with no UART data errors.
Perhaps there is a frequency closer to 25 Mhz that will produce no errors with modulation but I can live with 23.9 Mhz CPU speed.