I see that TI have a white paper to compare and contrast the MSP4300 against the Microchip XLP
http://focus.ti.com/general/docs/lit/getliterature.tsp?literatureNumber=slay015&fileType=pdf
Does TI have a similar publication to benchmark against the Atmel picoPower ATmega164PA? Here is the datasheet to that part.
http://www.atmel.com/dyn/resources/prod_documents/doc8272.pdf
The application requires that the MCU be in sleep mode mostly, wake up at defined periods (us resolution), communicate with a radio, go back to sleep, while doing around 10 ADC samples per second.