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Since you asked this in the MSP430 forum, I can say that no, there are no MSPs with two USB2.0 interfaces.
MSPs have at most one USB interface and act only as USB client, not as host. Also, even the fastest MSPs are not fast enough to utilize USB2.0 speed.
MSPs are ultra-low-power, not ultra-high-preformance devices (even if they are ultra-high-performant in relation to their ultra-low-power consumption).
You might find something in the stellaris series.
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