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TPS61091: What happens if VBAT is 5V on the 3.3V version(TPS61091RSA)?

Part Number: TPS61091
Other Parts Discussed in Thread: TPS63802

We have a design with a TPS61091RSA which is powered with 5V on VBAT. We expected a output on VOUT of 3.3V.  If we power it with 1.8V the ouput is as expected 3.3V. Is this chip able to Buck Convert?