As for input voltage for VEN of TPS259541DSGR, the datasheet says as below;
"For supply voltages greater than 6V, it is recommended to use an appropriate resistor divider
between IN, EN and GND to ensure the voltage at the EN pin is within the specified limits."
The maximum voltage for enable pin is specified as 6V.
Below schematic is from TPS2595EVM manual.
Q1) When using 12V as VIN, the enable pin voltage is likely to exceed the recommended operating range, i.e, 0V to 6V because
only 1M ohm pull-up resistor is connected to VIN. Is it working fine under 12V input condition?
Q2) As to TPS259541, is there a way to disable undervoltage lockout feature?
Your kind advisement would be thankful.
Jaewon.