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TPS2660: Schottky selection tips

Part Number: TPS2660

Tool/software:

According to tips, some questions need your clarification.

1. Can we choose 100V to use if diode blocking voltage of my current case is 80V? It's better, right? Or it's not critical and jsut make sure higher than Vin (48V my case).

3. Does min of vout pin like below?